Experimental organic chemistry - Doyle, Michael P.; Mungall, William S. (New York Wiley, 1980)
Table of Contents: Introduction -- 1. Separations of Organic Compounds -- 2. Recrystallization and Melting Point Ranges -- 3. Separation Techniques: Isolation of Trimyristin from Nutmeg -- 4. The Preparation and Purification of Myristic Acid -- 5. Steam Distillation: Isolation of Limonene -- 6. Fractional Distillation: Purification of Limonene -- 7. Observing Chemical Reactions: Solubility Tests, Chemical Characterization Tests, and Thin Layer Chromatography -- 8. Substitution Reactions of Organic Compounds: Preparation of 3-Chloro-3-Methylpentane -- 9. Elimination Reactions of Organic Compounds: Preparation of 3-Methyl-2-Pentene -- 10. Product Analysis: Gas-Liquid Partition Chromatography -- 11. Addition Reactions of Organic Compounds: Preparation of 3-Bromo-3Methylpentane -- 12. Infrared Spectroscopy -- 13. Structural Identification of Organic Compounds -- 14. Oxidation Reactions of Organic Compounds: Oxidation of Alcohols -- 15. The Grignard Synthesis: Preparation of 1,2-Diphenylethanol -- 16. Dehydration of 1,2-Diphenylethanol -- 17. Friedel-Crafts Reactions: Preparations of 1,3-Dimethyl-5-tert-Butylbenzene and 2,4-Dimethylacetophenone -- 18. Nuclear Magnetic Resonance Spectroscopy -- 19. Column Chromatography: Synthesis and Purification of o-Nitrophenol -- 20. Diazotization of 2,5-Dichloroaniline: Preparation of 2,5-Dichlorophenol -- 21. Identification of Organic Compounds Containing Carbon, Hydrogen, and Halogen -- 22. Identification of Organic Compounds Containing Carbon, Hydrogen, and Oxygen -- 23. Identification of Organic Compounds Containing Carbon, Hydrogen, and Nitrogen -- 24. Identification of Carboxylic Acids and Carboxylic Acid Derivatives -- 25. Identification of a General Unknown -- 26. Separation and Identification of the Components of a Mixture -- 27. Phase Transfer Catalysis in the Synthesis of 7,7-Dichlorobicyclo [4.1.0]heptane -- 28. Multistep Organic Synthesis: Preparation of Benzocaine -- 29. Condensation Reactions: Synthesis of Coumarin-3-Carboxylic Acid -- 30. Electronic Absorption Spectroscopy -- 31. Use of Protective Groups in Organic Synthesis: Preparation of 4,4-Diphenyl-3-buten-2-one -- 32. Stereoselectivity in Reductions of 3-Methylcyclohexanone -- 33. The Association of Ceric Ion with Benzyl Alcohol: The Equilibrium Expression and Equilibrium Constant -- 34. Ceric Ion Oxidation of Benzyl Alcohol: The Rate Law and Rate Constant -- 35. An Enzyme-Catalyzed Reaction: Hydrolysis of Urea -- 36. Polarimetry: Hydroboration-Oxidation of (+)-a-pinene -- 37. Diels-Alder Reactions: Synthesis of cis-4-Methyl-4-cyclohexene-1,2-dicarboxylic Acid Anhydride -- 38. Polymers and Polymerization -- 39. Multistep Organic Syntheses: Formation and Reactions of Diethyl a-Acetoglutarate -- 40. Use of the Chemical Literature for Organic Syntheses -- Appendix A. Table of Selected Organic Compounds with Their Physical Constants and Derivatives -- Appendix B. Characteristic Infrared Absorptions for Organic Compounds -- Appendix C. Characteristic Proton NMR Spectral Positions for Organic Compounds -- Useful References -- Index.
Keywords: Chemistry, Organic -- Laboratory manuals