Catalytic kinetics chemistry and engineering - Murzin, Dmitry 1963-; Salmi, Tapio (Amsterdam, Netherlands Elsevier, 2016)
History -- Catalysis -- Formal Kinetics -- Acquisition of Kinetic Data -- Kinetics and Thermodynamics -- Examples and Exercises -- Homogeneous Catalysis -- Heterogeneous Catalysis -- Organocatalysis -- Examples and Exercises -- Reaction Rate Theory -- Elementary Reactions in Solutions -- Reaction Mechanism -- Quasi-equilibrium Approximation -- Relationship Between Thermodynamics and Kinetics -- Transition State Theory of Surface Reactions -- Rates of Reactions on Nonideal Surfaces -- Deterministic and Stochastic Models -- Microkinetic Modeling -- Compensation Effect -- Isotope Effects -- Examples and Exercises -- Steady State Kinetics of Complex Reactions -- Basic Routes of Complex Reactions -- Single-Route Steady-State Reaction -- Topological Analysis of Complex Reactions -- Electrical Analogy of Reaction Networks -- Thermodynamic Consistency of Rate Constants for Complex Networks -- Kinetic Aspects of Selectivity -- Parallel Reactions: Kinetic Coupling -- Reduction of Complexity -- Polynomial Kinetics -- Examples and Exercises -- Homogeneous Acid-Base Catalysis -- Nucleophilic Catalysis -- Catalysis by Metal Ions -- Catalysis by Organometallic Complexes -- Organocatalysis -- Polymerization Catalysis -- Enzymatic Catalysis -- Cooperative Kinetics -- Inhibition -- Effects of pH -- Single Molecule Enzymology -- Enantioselectivity in Enzyme Catalyzed Reactions -- Generalized Rate Laws for Enzymatic Reactions -- Heterogeneous Systems/Immobilized Enzymes -- Examples and Exercises -- Reactions on Ideal Surfaces -- Reactions on Nonideal Surfaces -- Selectivity -- Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- Solvent Effects -- Ionic Species -- Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- Electrocatalytic Kinetics -- Photocatalytic Kinetics -- Nanokinetics -- Examples and Exercises -- General -- Combined Catalytic and Noncatalytic Reactions -- Multiple Catalysts of the Same Type -- Multiple Catalysts of Different Types -- Examples and Exercises -- Transient Kinetics -- Relaxation Methods -- Temperature-Programmed Desorption --Oscillations -- Dynamic Catalyst Changes -- Examples and Exercises -- Catalytic Multi-Phase Systems -- Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- Catalytic Two-Phase Systems -- Mass Transfer and Enzymatic Kinetics -- External Mass Transfer -- Internal Diffusion and Selectivity -- Internal Diffusion and Deactivation -- Elucidation of the Impact of Mass Transfer -- Three-Phase Systems -- Basic Principles -- Heuristic Design of Experiments -- Parameter Estimation: Classical Methods -- Parameter Estimation: Regression -- Numerical Strategies -- Analysis of Parameters -- Model Discrimination -- Software -- Case Studies.
Includes bibliographical references and index.
Keywords: Catalysis; Chemical kinetics